GENERATION AND REACTIONS OF AZA-ORTHO-XYLYLENES.

Aza-ortho-xylylene - benzazetine valence isomerization.

Theoretical studies
Kolshorn H. and Meier H., Z. Naturforsch., 32a, 780 (1977).
Morawietz J., Sander W. and Traubel M., J. Org. Chem., 60,6368 (1995).
Sander W. and Morawietz J., Tetrahedron Lett., 34,1913 (1993)
Pfister-Guillouzo G., Gracian F., Senio A., Letulle M. and Ripoll J.-L., Tetrahedron Lett, 33, 5753 (1992).

E/Z-isomerization of the exocyclic imine group.
Morawietz J., Sander W. and Traubel M., J. Org. Chem., 60,6368 (1995).

Benzocyclobutenes
Michellys P. Y., Pellissier H. and Santelli M., Org. Prep. Proced. Intl., 28, 545 (1996).

Benzothietes
Meier H., J. Prakt. Chem., 338, 383 (1996) 



[1,4] Hydrogen shift in carbenes and nitrenes

[1,4]-hydrogen shift in 2-aminophenylcarbene

Morawietz J., Sander W. and Traubel M., J. Org. Chem., 60,6368 (1995).
Sander W. and Morawietz J., Tetrahedron Lett., 34,1913 (1993).
Murata S., Sugawara T. and Iwamura H., J. Am. Chem. Soc., 107,6317 (1985). 


Generation and reactions of aza-ortho-xylylenes