Sugars in the synthesis of natural
products
PASZKÓWKA, 8-13 June 2005
PROGRAMME
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Wednesday, June 08, 2005 |
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Arrival of participants to Paszkówka |
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19.00 |
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Welcome banquet |
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Thursday, June 09, 2005 |
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8.00 – 9.00 |
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Breakfast |
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9.00 – 9.10 |
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Opening – Marek Chmielewski |
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Chairman: Marek
Chmielewski |
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9.10 – 9.50 |
PL 01 |
Pierre Sinaÿ (Ecole Normale Supérieure), Molecular
surgery on perbenzylated saccharides and cyclodextrines. |
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9.50 – 10.30 |
PL 02 |
Janusz
Jurczak (IOC PAS), Highly diastereoselective
synthesis of azasugars starting from α-amino aldehydes. |
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10.30 – 10.40 |
OP 01 |
Jacek
M³ynarski (IOC PAS), Ketene dithioacetals as versatile intermediates
for one carbon homologation of carbohydrates: synthesis of 3-deoxy-2-ulosonic
acids. |
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10.40 – 10.50 |
OP 02 |
Jessica
Richter (Westfäliche Wilhelms Universität), Vinyloxy-alkoxides – new
powerful reagents for stereoselective C-C bond formation. |
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10.50 – 11.20 |
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Coffee break |
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Chairman: Francesco Nicotra |
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11.20 – 12.00 |
PL 03 |
Joachim
Thiem (University of Hamburg), Convenient synthesis of complex oligosaccharides by use of
trans-sialidase. |
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12.00 – 12.40 |
PL 04 |
Serafin
Valverde (Instituto de Química Orgánica
General), Design
of a scaffold based on carbohydrates: An approach to natural product mimics. |
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12.40 – 12.50 |
OP 03 |
Piotr
Kwiatkowski (IOC PAS), Application of metalosalen complexes to
asymmetric catalysis under high-pressure conditions. |
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12.50 – 13.00 |
OP 04 |
Christine
Hoben (Universitaet Mainz), Synthesis of liquid- and solid-phase
catalysts for enantioselective transformations based on carbohydrates. |
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13.00 – 13.10 |
OP 05 |
Arkadiusz
Listkowski (IOC PAS), Towards macrocyclic sucrose derivatives with C2
– symmetry. |
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13.10 – 15.00 |
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Lunch |
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Chairman: Joachim Thiem |
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15.00 – 15.40 |
PL 05 |
Andreas
Kirschning (Universiy of Hannover), The liaison between hypervalent
iodine reagents and carbohydrate chemistry. |
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15.40 – 16.20 |
PL 06 |
Amelia
Pilar Rauter (Universidade de Lisboa), Biodiversity exploitation for the search of
bioactive sugars. |
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16.20 – 16.30 |
OP 06 |
Bart³omiej
Furman (IOC PAS), Rhodium-catalyzed intramolecular conjugate addition
of vinylstannanes to 2,3-dihydro-4-pyridones. An efficient route to
stereoselective construction of azabicyclic ring systems. |
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16.30 – 16.40 |
OP 07 |
Agnes
Scudlo (Universität Hamburg), Enzymatic sialylation of Galβ1-3GalNAc
derivatives leading to bioactive structures. |
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16.40 – 16.50 |
OP 08 |
Sébastien
Tardy (Institut de
Chimie Organique et Analytique), Synthesis
of sugar-derived N-vinyl oxazolidine-2-thiones as templates for
stereocontrolled cycloadditions. |
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16.50 – 17.00 |
OP 09 |
Cristina
Airoldi (University
of Milano-Bicocca), Design, synthesis and biological evaluation of
sugar-derived RAS inhibitors. |
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Friday, June 10, 2005 |
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Chairman: S³awomir Jarosz |
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9:00 – 9:40 |
PL 07 |
Horst
Kunz (Universitaet Mainz), The function of carbohydrates in fully
synthetic glycopeptide antitumour vaccines. |
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9.40 – 10.20 |
PL 08 |
Marek
Chmielewski (IOC PAS), An entry to oxygen analogs of penicillin and
cephalosporin. |
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10.20 – 10.30 |
OP 10 |
Bartosz
Lewandowski (IOC PAS), Synthesis of
macrocyclic receptors containing sucrose scaffold. |
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10.30 – 10.40 |
OP 11 |
Thomas
Jöge (Universiy of
Hannover), Novel oligoaminoglycosides. |
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10.40 – 10.50 |
OP 12 |
Magdalena
Dziedzic (IOC PAS), The stannyl-Prins reaction. |
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10.50 – 11.20 |
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Coffee break |
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Chairman: Horst Kunz |
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11.20 – 12.00 |
PL 09 |
Inge
Lundt (Technical University of Denmark), From
sugars to sugar mimics: stereoselective synthesis of aminocyclopentanols as
glycosidase inhibitors. |
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12.00 – 12.40 |
PL 10 |
Jose
Fuentes Mota (Universidad de Sevilla), Azasugars and azaspironucleosides. |
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12.40 – 12.50 |
OP 13 |
Wojciech
Cha³adaj (IOC PAS), Enantioselective allylation of
acitvated aldehydes catalyzed by (salen)Cr(III) complexes. |
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12.50 – 13.00 |
OP 14 |
Ákos
Szilágyi (University
of Debrecen), Analogs of the DNA-cleaving antibiotic leinamycin. |
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13.00 – 15.00 |
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Lunch |
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Chairman: Serafin Valverde |
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15.00 – 15.40 |
PL 11 |
Patrick
Rollin (Université d’Orléans), Synthesis of glucosinolates,
chemical and biological tags in Brassicales. |
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15.40 – 16.20 |
PL 12 |
Hermen S.
Overkleeft (Leiden University), Synthesis of
glyco-amino acids and peptides. |
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16.20 – 16.30 |
OP 15 |
José M.
Illangua (Universidad de
Sevilla), Spironucleosides and pseudospironucleosides. |
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16.30 – 16.40 |
OP 16 |
Yves
Blériot (Ecole Normale Supérieure),
Synthesis and biological evaluation of some higher homologues of known potent
iminosugar-based glycosidase inhibitors. |
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16.40 – 16.50 |
OP 17 |
Wioletta
Koœnik (IOC PAS), Anomeric hydroperoxides; synthesis, enantioselective
epoxidation. |
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16.50 – 17.00 |
OP 18 |
Aitor
Barrio (Instituto de
Química Orgánica General), Synthesis of C-glycals via diethylzinc-mediated umpolung of p-allyl palladium derived from 1-exo-methylene
2,3-anhydrofuranoses. |
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Saturday, June 11, 2005 |
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All day - trip to Krakow |
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Sunday, June 12, 2005 |
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Chairman: Janusz Jurczak |
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9:00 – 9:40 |
PL 13 |
Francesco Nicotra (Università degli Studi di Milano-Bicocca), Glycidic scaffolds in drug research. |
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9.40 – 10.20 |
PL 14 |
S³awomir
Jarosz (IOC PAS), What can be done from sucrose??? |
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10.20 – 10.30 |
OP 19 |
Filipa
Marcelo (Universidade de Lisboa), Approaches towards the synthesis of
miharamycins sugar moiety. |
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10.30 – 10.40 |
OP 20 |
Sebastian
Stecko (IOC PAS), A double asymmetric induction in 1,3-dipolar
cycloaddition of a cyclic nitrones derived from malic acid and tartaric acid
with unsaturated γ-lactones. |
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10.40 – 10.50 |
OP 21 |
Joanna
Cha³ko (University of Warsaw), Highly
diastereoselective allylation of chiral oxime ethers. |
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10.50 – 11.20 |
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Coffee
break |
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Chairman:
Inge Lundt |
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11.20 – 12.00 |
PL 15 |
Yves
Queneau (Laboratoire de Chimie Organique), Recent progress in the
preparation of some glycoconjugates and analogues from easily available
carbohydrate based-synthons. |
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12.00 – 12.40 |
PL 16 |
Paul
Kosma (Univ. of Natural Resources and Applied Life
Sciences), Synthesis and antibody recognition of
chlamydial lipopolysaccharide. |
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12.40 – 12.50 |
OP 22 |
Leendert
J. van den Bos (Leiden University), Thioglycuronides: synthesis and application
in the assembly of acidic oligosaccharides. |
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12.50 – 13.00 |
OP 23 |
Anna
Gawe³ (IOC PAS), Functionalization
of the homoallylic bridge in higher sugar precursors. |
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13.00 – 15.00 |
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Lunch |
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Chairman:
Pierre Sinaÿ |
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15.00 – 15.40 |
PL 17 |
Pál
Herczegh (University of Debrecen), Synthesis of structural analogs of natural
products. |
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15.40 – 16.20 |
PL 18 |
Hartmut
Redlich (Institut der Westfälischen Wilhelms-Universität), Trimethylene
Dithioacetals of Carbohydrates: New Developments. |
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16.20 – 16.30 |
OP 24 |
Marcin
Nowogródzki (IOC PAS), A convenient route to highly oxidized
carbobicycles from sugar allyltins. |
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16.30 – 16.50 |
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Cristobal
López, (Instituto
de Química Orgánica General), Iterative, orthogonal strategy for oligosaccharide synthesis based on
the regioselective glycosylation of triol acceptors with partially
unprotected n-pentenyl-orthoesters. |
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16.50 – 17.00 |
OP 25 |
Tomasz Ba³akier (University of Warsaw), Lewis acid catalyzed diastereoselective
allylation of chiral activated ketones. |
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